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Ass. Lect. Maha Abd Elsalam Mohamed Attallah :: Publications:

Title:
Tailoring the electrochemical performance of the polymer electrolyte using Na2H20B4O17 for magnesium sulfur battery applications
Authors: M.A.Attallah, E.sheha
Year: 2025
Keywords: Solid electrolyte Magnesium sulfur battery Na2H20B4O17 Energy storage, Solid electrolyte,Magensium sulfur battery
Journal: Current Applied Physics
Volume: 71
Issue: 1567-1739
Pages: 175-183
Publisher: Elsevier
Local/International: International
Paper Link:
Full paper Maha Abd Elsalam Mohamed Attallah _electrolyte.pdf
Supplementary materials Not Available
Abstract:

Due to the construction’s low cost, ecological appeal, friendliness, great theoretical density, and reliability, the Mg-S battery is an encouraging substitute for the pillar lithium battery. Nevertheless, self-discharge, the delayed conversion reaction pathway, and the absence of readily compatible electrolytes continue to restrict its beneficial uses. In this work, polymer electrolyte used 0.7 wt% polyvinyl alcohol (PVA), (0.3-x)wt.%(Mg(CF3SO3)2) and xwt. %Na2H20B4O17 (x = 0,0.01,0.02,0.03,0.04,0.05) (PEx) have been prepared and characterized for usage in Mg-S batteries. Integrating the PVA_(0.3-x)wt.% (Mg(CF3SO3)2)_ 0.04Na2H20B4O17 (X4) with tetraethylene glycol dimethyl ether (G4) demonstrates effective Mg plating and stripping behavior, good anodic stability (versus Mg/ Mg 2+), and a significant ionic conductivity (8.09 × 10− 7 S cm− 1 at 323 K). The Mg-S is assembled using an X4_G4 electrolyte and delivers a reversible capacity of 100 mAh g− 1 after 30 cycles

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