In this work, a supercritical carbon dioxide assembly was successfully constructed for dyeing Nylon6 fabric. Primary experiments were carried out to confirm the possibility of bringing the dyeing up to factory scale. A series of disperse azo dyes with potential antibacterial activity were applied to dye the fabric under our study in supercritical carbon dioxide (scCO2). The factors affecting the dyeing conditions (i.e., dye concentration, time, temperature and pressure) and functional properties were discussed and compared with those in aqueous dyeing. The comparison revealed that elimination of auxiliary chemicals such as salt, carrier or dispersing agent has no diverse effect on dyeing. The color strength of the dyed fabric evaluated by using K/S measurements increased by increasing dye concentration from 2% to 6% owf. (on weight of fabric). The nylon6 fabrics dyed in supercritical carbon dioxide have good fastness properties, and especially light fastness compared with conventional exhaustion dyeing. Antibacterial activity of the dyed samples under supercritical conditions was evaluated and the results showed excellent antibacterial efficiency. |
