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Prof. Mahmoud Ahmed Mohamed Mousa :: Publications: |
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| Title: | Interaction of ditertiary phosphines with phenyl- and 1-naphthyldithiocarbamatonickel(II) |
| Authors: | Aref AlyAhmed Abdelraouf Mohamed Mahmoud Mousa Mohamed El-Shabasy |
| Year: | 1985 |
| Keywords: | Science |
| Journal: | Collection of Czechoslovak Chemical Communication |
| Volume: | 50 |
| Issue: | 6 |
| Pages: | 1383-1390 |
| Publisher: | Not Available |
| Local/International: | International |
| Paper Link: | Not Available |
| Full paper | Not Available |
| Supplementary materials | Not Available |
| Abstract: |
The synthesis of the following mixed ligand complexes is reported: [Ni(phdtc)2(dpm)2], [Ni(phdtc)2(dpe)2], [Ni(phdtc)2(dpp)3], [Ni(1-naphdtc)2(dpm)2], [Ni(1-naphdtc)2], and [Ni(1-naphdtc)2(dpp)2], where phdtc = PhNHCSS-, 1-naphdtc = 1-NaPhNHCSS-, dpm = Ph2PCH2PPh2, dpe = Ph2P(CH2)2PPh2, and dpp = Ph2P(CH2)3PPh2. The complexes are characterised by microanalysis, IR and UV-Vis spectra, magnetic measurements, conductivity, X-ray powder diffraction, and thermal analysis. All the mixed ligand complexes are diamagnetic, and thus a square-planar or square-pyramidal (low-spin) structure was proposed for the present complexes. |
