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Dr. Mohamed Abd El-Rahman Mousa Abo-Riya :: Publications:

Title:
Synthesis, surface properties and biological activity of N,N,N-tris(hydroxymethyl)-2-oxo-2- (2-(2-(alkanoyloxy) ethoxy)ethoxy) ethanaminium chloride surfactants
Authors: Ismail Aiad , M. Abo Riya , Salah M. Tawfik, Mahmoud A. Abousehly
Year: 2015
Keywords: Cationic surfactants; Surface; Biological activity; Sulfate reducing bacteria; Emulsification
Journal: Egyptian Journal of Petroleum
Volume: doi:10.1016/j.ejpe.2015.07.020
Issue: Not Available
Pages: Not Available
Publisher: www.elsevier.com
Local/International: International
Paper Link:
Full paper Not Available
Supplementary materials Not Available
Abstract:

A new series of some cationic surfactants were synthesized namely: 2-(2-(2-(dodecanoy loxy)ethoxy)ethoxy)-N,N,N-tris(hydroxymethyl)-2-oxoethanaminium (DDAC); N,N,N-tris(hydro xymethyl)-2-oxo-2-(2-(2-(tetradecanoyloxy) ethoxy)ethoxy) ethanaminium (TDAC) and N,N,N-tr is(hydroxymethyl)-2-oxo-2-(2-(2- hexadecanoyloxy)ethoxy)ethoxy)ethanaminium (HDAC). The chemical structures of the synthesized cationic surfactants were confirmed using FT-IR and 1H-NMR spectroscopies. The surface tension of the synthesized cationic surfactants was measured at 25, 40 and 55 C. The surface parameters were determined from the surface tension measurements. The emulsification power and foaming power measurements showed the applicability of these surfactants in the oil field. The biological activity of the synthesized surfactants was measured against pathogenic bacteria (Staphylococcus aureus and Escherichia coli) and fungi (Candida albicans and Aspergllus niger) using inhibition zone diameters. The obtained data revealed that the dodecanoate derivative (DDAC) has more antimicrobial activity against the investigated microorganisms than tetradecanoate and hexadecanoate derivatives (TDAC and HDAC).

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