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Prof. Mohamed Azab :: Publications: |
Title: | Azeotropy in terpolymerisation reactions of tributyltin acrylate or methacrylate with itaconic acid or dimethylitaconate and N‐vinyl‐2‐pyrrolidone |
Authors: | MM Azab |
Year: | 1993 |
Keywords: | Not Available |
Journal: | Polymer international |
Volume: | 32 |
Issue: | Not Available |
Pages: | 283-288 |
Publisher: | Not Available |
Local/International: | International |
Paper Link: | |
Full paper | Not Available |
Supplementary materials | Not Available |
Abstract: |
Ternary copolymerisations of tri-n-butyltin acrylate (TBTA) or tri-n-butyltin methacrylate (TBTMA) with itaconic acid (IA) or dimethylitaconate (DMI) and N-vinyl-2- pyrrolidone (NVP) were carried out in solution at 70 C in the presence of a free radical initiator. Experimental, terpolymerisation data agreed with calculations based on the Alfrey- Goldfinger equation. Ternary azeotropic compositions for TBTA-IA-NVP and TBTA-DMI-NVP systems were 52.60: 14.80: 32.60 and 56.60: 26.60: 16.80 mol%, respectively. Also ' ... |