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Prof. Mohamed Abd-Elfattah Gabal :: Publications:

Title:
Zn-Cr Co-Substitution Effect on Structural and Electromagnetic Properties of CuFe2O4 via Oxalate Decomposition Route
Authors: Mohamed Gabal*
Year: 2016
Keywords: conductivity; electromagnetic properties; thermal decomposition; ferrites
Journal: Int. J. Appl. Ceram. Technol.,
Volume: 13
Issue: 4
Pages: 763–772
Publisher: Not Available
Local/International: International
Paper Link: Not Available
Full paper Mohamed Abd-Elfattah Gabal_gabal 44.pdf
Supplementary materials Not Available
Abstract:

Zn-Cr-co-substituted Cu1-xZnxFe2-2xCr2xO4 ferrites (where x = 0.0–0.5) were prepared via thermal decomposition of oxalate precursors. The thermal decomposition up to ferrites formation was followed by differential thermal analysis–thermogravimetry measurements. M€ossbauer technique was used to predict the possible cation distribution of the entire system, and X-ray diffraction, Fourier transform infrared, and electromagnetic measurements were used for confirmation. The superparamagnetic characteristics estimated via M€ossbauer studies, for samples with higher substitution, agreed well with vibrating sample magnetometer, magnetic susceptibility, and conductivity results. All the samples showed semiconducting properties in which conductivity decreases by increasing substitution. The effect of cationic substitution on the entire system was investigated and discussed.

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