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Dr. Mohamed Nabil Abd Elmonaem Mohamed Diab :: Publications:

Title:
Surface modification of CdSe nanocrystals: Application to polymer solar cell
Authors: M. Nabila, Shaimaa A. Mohamedb,c,d,∗, K. Easawia, Salah S.A. Obayyac, S. Negm,M.K. El-Mansyfa, H. TalaatM. Nabil, Shaimaa A. Mohamed, K. Easawi, Salah S.A. Obayya, S. NegmM.K. El-Mansy, H. Talaat
Year: 2020
Keywords: Photovoltaic CdSe nanocrystal Surface passivation Iodide ligand
Journal: current applied physics
Volume: 20
Issue: 3
Pages: 470-476
Publisher: Elsevier
Local/International: International
Paper Link:
Full paper Mohamed Nabil Abd Elmonaem Mohamed Diab_1-s2.0-S1567173920300018-main.pdf
Supplementary materials Not Available
Abstract:

The optimum choice of the ligand that stabilizes the colloidal quantum dots and passivate the surface is crucial for tuning the energy level and remain elusive. The atomic ligand passivation with iodide remains superior over other surface treatments. Herein, we applied the iodide ligand to passivate the CdSe nanocrystals with an excitonic absorption at 2.1 eV by a liquid-liquid extraction process. We took the view of the change in the optical and structural properties upon ligand exchange. Finally, we tested the performance of the iodide treated dots by employing it in an inverted structure polymer solar cell based on P3HT: PCBM.

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