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Dr. Shahera Mohamed Gamal Edin Shohyeb :: Publications: |
Title: | Synthesis and Characterization of Some New Binary and Ternary Copper Complexes: X-Ray Crystal Structural of Dioxo Dinuclear Bipyridine Copper Complex |
Authors: | Ramadan M. Ramadan, Shahera M. Shohayeb & Rania G. Mohamed |
Year: | 2013 |
Keywords: | 2,2′bipyridine, amino acids, copper complexes, crystal structure, EPR analysis |
Journal: | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry |
Volume: | 43 |
Issue: | 5 |
Pages: | pages 609-616 |
Publisher: | The online platform for Taylor & Francis Group content |
Local/International: | International |
Paper Link: | |
Full paper | Not Available |
Supplementary materials | Not Available |
Abstract: |
Binary and ternary copper complexes were synthesized from the reactions of Cu(NO3)2, amino acids (N-acetylvaline, av, N- acetylphenylalanine, apa, and N-acetyltryptophan, atp), and heterocyclic nitrogen ligands (2,2′-bipyridine, bpy, and 1,10-phenanthroline, phen). The complexes have been characterized by elemental analysis, IR, EPR, and mass spectrometry. The dioxo dinuclear bipyridine copper complex was studied by X-ray structure analysis. The analysis revealed that it crystallized in the triclinic space group P1 with a Z value of 1. The crystal packing showed three-dimensional supramolecular arrangements of the molecules stabilized by intra- and intermolecular hydrogen bonds. |